32/64 bit keys are interchangeable. The disks are the only things different. A 32-bit Home Premium key, for example, will work with no problems (activation or otherwise) when used with a 64-bit installation. Just some food for thought.
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Athlon 64 X2 5000+ Black Edition OC'd 3.2GHz
Asus M3A32-MVP Deluxe/WiFi
4GB Geil PC6400 2x2 Kit
Sapphire Radeon HD 2900 XT
Creative X-FI XtremeGamer
WD 250GB 2500KS SATA-II
WD 500GB 5000AAKS SATA-II
Samsung SH203-B SATA DVD-RW
Thermaltake ToughPower 750W
Antec P182
Windows Vista 64-Bit Home Premium